| Direct H2S, HS- and pH Measurements of High-Temperature Hydrothermal Vent Fluids With In Situ Raman Spectroscopy | |
Li, Lianfu1,2,3 ; Li, Zimeng1,4; Zhong, Richen4; Du, Zengfeng1,3; Luan, Zhendong1,3; Xi, Shichuan1,3; Zhang, Xin1,2,3
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| 2023-05-16 | |
| 发表期刊 | GEOPHYSICAL RESEARCH LETTERS
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| ISSN | 0094-8276 |
| 卷号 | 50期号:9页码:9 |
| 通讯作者 | Zhang, Xin([email protected]) |
| 摘要 | Hydrothermal H2S is an important energy source for hydrothermal ecosystems. However, it is difficult to obtain accurate hydrogen sulfide concentrations in high-temperature hydrothermal fluids because they are highly susceptible to oxidation and compositional variability with mixing. In this study, a new in situ approach for measuring H2S, HS- and pH in hydrothermal fluids was developed and applied to the detections of Okinawa Trough hydrothermal activities. The in situ total H2S concentrations in the Jade and Biwako fluids were determined to be 31.4 and 76.7 mmol/kg, respectively. The in situ measured pH of the Jade fluids was determined to be 6.3, which has exceeded that of a neutral fluid at a specific temperature and pressure, indicating that the pH of Jade fluids is weakly alkaline. The pH transition of hydrothermal fluids from alkaline to acidic may be attributed to the thermal decomposition of organic matter and sulfide precipitation. |
| 关键词 | hydrothermal fluids in situ detection in situ pH H2S Raman spectroscopy |
| DOI | 10.1029/2023GL103195 |
| 收录类别 | SCI |
| 语种 | 英语 |
| 资助项目 | National Natural Science Foundation of China[42106184]; National Natural Science Foundation of China[92058206]; National Natural Science Foundation of China[42221005]; National Natural Science Foundation of China[41822604]; Strategic Priority Research Program, CAS[XDA22050102]; Young Taishan Scholars Program[tsqn201909158]; China Postdoctoral Science Foundation[2020M682245]; Natural Science Foundation of Shandong Province[ZR2021QD046] |
| WOS研究方向 | Geology |
| WOS类目 | Geosciences, Multidisciplinary |
| WOS记录号 | WOS:000999862600002 |
| 出版者 | AMER GEOPHYSICAL UNION |
| WOS关键词 | MOLAL THERMODYNAMIC PROPERTIES ; DEGREES-C ; GEOCHEMICAL CONSTRAINTS ; TRANSPORT-PROPERTIES ; HIGH-PRESSURES ; DISSOLVED H-2 ; TROUGH ; DISSOCIATION ; STABILITY ; CHEMISTRY |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.qdio.ac.cn/handle/337002/182467 |
| 专题 | 海洋地质与环境重点实验室 |
| 通讯作者 | Zhang, Xin |
| 作者单位 | 1.Chinese Acad Sci, Ctr Deep Sea Res, CAS Key Lab Marine Geol & Environm, Inst Oceanol,Ctr Ocean Mega Sci, Qingdao, Peoples R China 2.LaoShan Lab, Lab Marine Geol, Qingdao, Peoples R China 3.Univ Chinese Acad Sci, Beijing, Peoples R China 4.Univ Sci & Technol Beijing, Sch Civil & Resource Engn, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Lianfu,Li, Zimeng,Zhong, Richen,et al. Direct H2S, HS- and pH Measurements of High-Temperature Hydrothermal Vent Fluids With In Situ Raman Spectroscopy[J]. GEOPHYSICAL RESEARCH LETTERS,2023,50(9):9. |
| APA | Li, Lianfu.,Li, Zimeng.,Zhong, Richen.,Du, Zengfeng.,Luan, Zhendong.,...&Zhang, Xin.(2023).Direct H2S, HS- and pH Measurements of High-Temperature Hydrothermal Vent Fluids With In Situ Raman Spectroscopy.GEOPHYSICAL RESEARCH LETTERS,50(9),9. |
| MLA | Li, Lianfu,et al."Direct H2S, HS- and pH Measurements of High-Temperature Hydrothermal Vent Fluids With In Situ Raman Spectroscopy".GEOPHYSICAL RESEARCH LETTERS 50.9(2023):9. |
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| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | ||
| Geophysical Research（1692KB） | 期刊论文 | 出版稿 | 限制开放 | CC BY-NC-SA | 浏览 | |
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