Regulating N Species in N-Doped Carbon Electro-Catalysts for High-Efficiency Synthesis of Hydrogen Peroxide in Simulated Seawater

doi:10.1002/advs.202302446

	Regulating N Species in N-Doped Carbon Electro-Catalysts for High-Efficiency Synthesis of Hydrogen Peroxide in Simulated Seawater
	Wang, Nan1 ; Ma, Shaobo 2; Zhang, Ruiyong 1; Wang, Lifei 1; Wang, Yanan 1; Yang, Lihui1 ; Li, Jianhua 1; Guan, Fang1 ; Duan, Jizhou1 ; Hou, Baorong 1
	2023-09-28
发表期刊	ADVANCED SCIENCE
页码	11
通讯作者	Zhang, Ruiyong([email protected]) ; Duan, Jizhou([email protected]) ; Hou, Baorong([email protected])
摘要	Electrochemical oxygen reduction reaction (ORR) is an attractive and alternative route for the on-site production of hydrogen peroxide (H2O2). The electrochemical synthesis of H2O2 in neutral electrolyte is in early studying stage and promising in ocean-energy application. Herein, N-doped carbon materials (N-Cx) with different N types are prepared through the pyrolysis of zeolitic imidazolate frameworks. The N-Cx catalysts, especially N-C800, exhibit an attracting 2e- ORR catalytic activity, corresponding to a high H2O2 selectivity (& AP;95%) and preferable stability in 0.5 m NaCl solution. Additionally, the N-C800 possesses an attractive H2O2 production amount up to 631.2 mmol g-1 h-1 and high Faraday efficiency (79.8%) in H-type cell. The remarkable 2e- ORR electrocatalytic performance of N-Cx catalysts is associated with the N species and N content in the materials. Density functional theory calculations suggest carbon atoms adjacent to graphitic N are the main catalytic sites and exhibit a smaller activation energy, which are more responsible than those in pyridinic N and pyrrolic N doped carbon materials. Furthermore, the N-C800 catalyst demonstrates an effective antibacterial performance for marine bacteria in simulated seawater. This work provides a new insight for electro-generation of H2O2 in neutral electrolyte and triggers a great promise in ocean-energy application. The synthesized graphite nitrogen doped carbon material delivers an attracting 2e- ORR catalytic activity in 0.5 m NaCl simulated seawater solution, corresponding to a high H2O2 selectivity (& AP;95%), preferable stability and H2O2 production amount up to 631.2 mmol g-1 h-1. Additionally, the prepared catalyst demonstrates an effective antibacterial performance for marine bacteria in simulated seawater.image
关键词	antibacterial hydrogen peroxide N-doped carbon oxygen reduction reaction simulated seawater
DOI	10.1002/advs.202302446
收录类别	SCI
语种	英语
资助项目	The present work was supported by the Special Research Assistant Program of the Chinese Academy of Sciences, Shandong Provincial Natural Science Youth Fund Project (ZR2022QD001, ZR2023QB193), the Key Research Program of Frontier Sciences, Chinese Academy o[ZR2022QD001]; The present work was supported by the Special Research Assistant Program of the Chinese Academy of Sciences, Shandong Provincial Natural Science Youth Fund Project (ZR2022QD001, ZR2023QB193), the Key Research Program of Frontier Sciences, Chinese Academy o[ZR2023QB193]; Special Research Assistant Program of the Chinese Academy of Sciences, Shandong Provincial Natural Science Youth Fund Project[ZDBS-LY-DQC025]; Key Research Program of Frontier Sciences, Chinese Academy of Sciences[41827805]; National Natural Science Foundation of China; Postdoctoral Innovation Project of Shandong Province and Applied Basic Research Programs of Qingdao
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science
WOS类目	Chemistry, Multidisciplinary ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS记录号	WOS:001072614400001
出版者	WILEY
WOS关键词	DIRECT H2O2 PRODUCTION ; OXYGEN REDUCTION ; AIR BATTERIES ; NITROGEN ; ALKALINE ; ELECTROCATALYSTS ; PERFORMANCE ; WATER
引用统计	被引频次：18[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.qdio.ac.cn/handle/337002/181732
专题	海洋环境腐蚀与生物污损重点实验室
通讯作者	Zhang, Ruiyong; Duan, Jizhou; Hou, Baorong
作者单位	1.Chinese Acad Sci, Inst Oceanol, CAS Key Lab Marine Environm Corros & Biofouling, 7 Nanhai Rd, Qingdao 266071, Peoples R China 2.Shandong Univ, Inst Frontier & Interdisciplinary Sci, Sci Ctr Mat Creat & Energy Convers, Qingdao 266237, Peoples R China
第一作者单位	中国科学院海洋研究所
通讯作者单位	中国科学院海洋研究所
推荐引用方式 GB/T 7714	Wang, Nan,Ma, Shaobo,Zhang, Ruiyong,et al. Regulating N Species in N-Doped Carbon Electro-Catalysts for High-Efficiency Synthesis of Hydrogen Peroxide in Simulated Seawater[J]. ADVANCED SCIENCE,2023:11.
APA	Wang, Nan.,Ma, Shaobo.,Zhang, Ruiyong.,Wang, Lifei.,Wang, Yanan.,...&Hou, Baorong.(2023).Regulating N Species in N-Doped Carbon Electro-Catalysts for High-Efficiency Synthesis of Hydrogen Peroxide in Simulated Seawater.ADVANCED SCIENCE,11.
MLA	Wang, Nan,et al."Regulating N Species in N-Doped Carbon Electro-Catalysts for High-Efficiency Synthesis of Hydrogen Peroxide in Simulated Seawater".ADVANCED SCIENCE (2023):11.