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Influence of chloride ion on depassivation of passive film on galvanized steel bars in concrete pore solution | |
Zheng, Haibing1,2,3; Dai, Jian-Guo2; Li, Weihua1; Poon, Chi Sun2 | |
2018-03-30 | |
发表期刊 | CONSTRUCTION AND BUILDING MATERIALS |
ISSN | 0950-0618 |
卷号 | 166页码:572-580 |
通讯作者 | Li, Weihua([email protected]) ; Poon, Chi Sun([email protected]) |
摘要 | This work aimed at studying the depassivation mechanism of the passive film on galvanized steel bar in concrete pore solution with different concentrations of chloride ion. The results showed that in a saturated Ca(OH)(2) solution, the critical chloride values for the depassivation of the passive films formed on galvanized steel bars and zinc metal specimens were 0.2 M and 0.3 M respectively. When the Cl- concentration was lower than the critical value, the donor density of the passive film increased and thus the protective property reduced with increasing the concentration of chloride ion, which could be interpreted by the point defect model (PDM). The corrosion products formed on the galvanized steel surface could inhibit the further ingress of the chloride ions and enhance the protective property, while such effect was not obvious for the zinc metal. (C) 2018 Elsevier Ltd. All rights reserved. |
关键词 | Chloride ions Passive film Corrosion Galvanized steel Concrete pore solution |
DOI | 10.1016/j.conbuildmat.2018.01.174 |
收录类别 | SCI |
语种 | 英语 |
资助项目 | Hong Kong Branch of National Engineering Research Center for Steel Construction[1-BBYP]###1616; Hong Kong Polytechnic University[1-ZVGE]###1617; National Science Fund for Distinguished Young Scholars[51525903]###200; Hong Kong Branch of National Engineering Research Center for Steel Construction[1-BBYP]; Hong Kong Polytechnic University[1-ZVGE]; National Science Fund for Distinguished Young Scholars[51525903] |
WOS研究方向 | Construction & Building Technology ; Engineering ; Materials Science |
WOS类目 | Construction & Building Technology ; Engineering, Civil ; Materials Science, Multidisciplinary |
WOS记录号 | WOS:000428491300053 |
出版者 | ELSEVIER SCI LTD |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.qdio.ac.cn/handle/337002/158463 |
专题 | 海洋环境腐蚀与生物污损重点实验室 |
通讯作者 | Li, Weihua; Poon, Chi Sun |
作者单位 | 1.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China 2.Hong Kong Polytech Univ, Dept Civil & Environm Engn, Kowloon, Hong Kong, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
第一作者单位 | 中国科学院海洋研究所 |
通讯作者单位 | 中国科学院海洋研究所 |
推荐引用方式 GB/T 7714 | Zheng, Haibing,Dai, Jian-Guo,Li, Weihua,et al. Influence of chloride ion on depassivation of passive film on galvanized steel bars in concrete pore solution[J]. CONSTRUCTION AND BUILDING MATERIALS,2018,166:572-580. |
APA | Zheng, Haibing,Dai, Jian-Guo,Li, Weihua,&Poon, Chi Sun.(2018).Influence of chloride ion on depassivation of passive film on galvanized steel bars in concrete pore solution.CONSTRUCTION AND BUILDING MATERIALS,166,572-580. |
MLA | Zheng, Haibing,et al."Influence of chloride ion on depassivation of passive film on galvanized steel bars in concrete pore solution".CONSTRUCTION AND BUILDING MATERIALS 166(2018):572-580. |
条目包含的文件 | ||||||
文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | ||
Influence of chlorid(2054KB) | 期刊论文 | 出版稿 | 限制开放 | CC BY-NC-SA | 浏览 |
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