Influence of chloride ion on depassivation of passive film on galvanized steel bars in concrete pore solution
Zheng, Haibing1,2,3; Dai, Jian-Guo2; Li, Weihua1; Poon, Chi Sun2
2018-03-30
发表期刊CONSTRUCTION AND BUILDING MATERIALS
ISSN0950-0618
卷号166页码:572-580
通讯作者Li, Weihua([email protected]) ; Poon, Chi Sun([email protected])
摘要This work aimed at studying the depassivation mechanism of the passive film on galvanized steel bar in concrete pore solution with different concentrations of chloride ion. The results showed that in a saturated Ca(OH)(2) solution, the critical chloride values for the depassivation of the passive films formed on galvanized steel bars and zinc metal specimens were 0.2 M and 0.3 M respectively. When the Cl- concentration was lower than the critical value, the donor density of the passive film increased and thus the protective property reduced with increasing the concentration of chloride ion, which could be interpreted by the point defect model (PDM). The corrosion products formed on the galvanized steel surface could inhibit the further ingress of the chloride ions and enhance the protective property, while such effect was not obvious for the zinc metal. (C) 2018 Elsevier Ltd. All rights reserved.
关键词Chloride ions Passive film Corrosion Galvanized steel Concrete pore solution
DOI10.1016/j.conbuildmat.2018.01.174
收录类别SCI
语种英语
资助项目Hong Kong Branch of National Engineering Research Center for Steel Construction[1-BBYP]###1616; Hong Kong Polytechnic University[1-ZVGE]###1617; National Science Fund for Distinguished Young Scholars[51525903]###200; Hong Kong Branch of National Engineering Research Center for Steel Construction[1-BBYP]; Hong Kong Polytechnic University[1-ZVGE]; National Science Fund for Distinguished Young Scholars[51525903]
WOS研究方向Construction & Building Technology ; Engineering ; Materials Science
WOS类目Construction & Building Technology ; Engineering, Civil ; Materials Science, Multidisciplinary
WOS记录号WOS:000428491300053
出版者ELSEVIER SCI LTD
引用统计
被引频次:45[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.qdio.ac.cn/handle/337002/158463
专题海洋环境腐蚀与生物污损重点实验室
通讯作者Li, Weihua; Poon, Chi Sun
作者单位1.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China
2.Hong Kong Polytech Univ, Dept Civil & Environm Engn, Kowloon, Hong Kong, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
第一作者单位中国科学院海洋研究所
通讯作者单位中国科学院海洋研究所
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GB/T 7714
Zheng, Haibing,Dai, Jian-Guo,Li, Weihua,et al. Influence of chloride ion on depassivation of passive film on galvanized steel bars in concrete pore solution[J]. CONSTRUCTION AND BUILDING MATERIALS,2018,166:572-580.
APA Zheng, Haibing,Dai, Jian-Guo,Li, Weihua,&Poon, Chi Sun.(2018).Influence of chloride ion on depassivation of passive film on galvanized steel bars in concrete pore solution.CONSTRUCTION AND BUILDING MATERIALS,166,572-580.
MLA Zheng, Haibing,et al."Influence of chloride ion on depassivation of passive film on galvanized steel bars in concrete pore solution".CONSTRUCTION AND BUILDING MATERIALS 166(2018):572-580.
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