Dichloridobis[N-(2-pyridylmethyl)-benzamide-kappa N-2,O]cadmium(II)

doi:10.1107/S1600536807031054

	Dichloridobis[N-(2-pyridylmethyl)-benzamide-kappa N-2,O]cadmium(II)
	Zhang, Shu-Fang ; Yang, Xiao-Gang ; Liu, Zhi ; Xu, Feng-Ling ; Hou, Bao-Rong
	2007-08-01
发表期刊	ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN	1600-5368
卷号	63 期号:Part 8 页码:M2058-U330
文章类型	Article
摘要	In the title compound, [CdCl2(C13H12N2O)(2)], the Cd-II ion is situated on an inversion centre, coordinated by two 0 atoms [Cd-O=2.3878 (17) angstrom] and two N atoms [Cd-N = 2.3404 (15) angstrom] from two N-(2-pyridylmethyl)benzamide ligands, and two Cl atoms [Cd-Cl = 2.5566 (6) angstrom], in a distorted octahedral geometry. In the crystal structure, intermolecular N-H center dot center dot center dot Cl hydrogen bonds [N center dot center dot center dot Cl = 3.1705 (18) angstrom] and pi-pi interactions, with a distance of 3.868 (3) angstrom between the centroids of the phenyl and pyridyl rings of neighbouring molecules, lead to the formation of two-dimensional layers parallel to the bc plane.; In the title compound, [CdCl2(C13H12N2O)(2)], the Cd-II ion is situated on an inversion centre, coordinated by two 0 atoms [Cd-O=2.3878 (17) angstrom] and two N atoms [Cd-N = 2.3404 (15) angstrom] from two N-(2-pyridylmethyl)benzamide ligands, and two Cl atoms [Cd-Cl = 2.5566 (6) angstrom], in a distorted octahedral geometry. In the crystal structure, intermolecular N-H center dot center dot center dot Cl hydrogen bonds [N center dot center dot center dot Cl = 3.1705 (18) angstrom] and pi-pi interactions, with a distance of 3.868 (3) angstrom between the centroids of the phenyl and pyridyl rings of neighbouring molecules, lead to the formation of two-dimensional layers parallel to the bc plane.
DOI	10.1107/S1600536807031054
URL	查看原文
收录类别	SCI
语种	英语
WOS记录号	WOS:000249692200027
引用统计	被引频次：1[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.qdio.ac.cn/handle/337002/6204
专题	海洋环境腐蚀与生物污损重点实验室
作者单位	1.Chinese Acad Sci, Inst Oceanol, Qingdao 266071, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 3.Qingdao Univ Sci & Technol, Coll Chem Engn, Qingdao 266042, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Shu-Fang,Yang, Xiao-Gang,Liu, Zhi,et al. Dichloridobis[N-(2-pyridylmethyl)-benzamide-kappa N-2,O]cadmium(II)[J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE,2007,63(Part 8):M2058-U330.
APA	Zhang, Shu-Fang,Yang, Xiao-Gang,Liu, Zhi,Xu, Feng-Ling,&Hou, Bao-Rong.(2007).Dichloridobis[N-(2-pyridylmethyl)-benzamide-kappa N-2,O]cadmium(II).ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE,63(Part 8),M2058-U330.
MLA	Zhang, Shu-Fang,et al."Dichloridobis[N-(2-pyridylmethyl)-benzamide-kappa N-2,O]cadmium(II)".ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE 63.Part 8(2007):M2058-U330.

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