Institutional Repository of Key Laboratory of Marine Environmental Corrosion and Bio-fouling, IOCAS
| Synthesis, crystal structure and electrochemical studies of two novel Zn(II) complexes of phthalic acid and imidazole derivatives | |
| Li Wei-Hua1,2; Zhao Guang-Fa1; Huang Zhao-Ge1; Liu Fa-Qian1; Ding Nai-Xu1; Liu Guang-Ye1 | |
| 2008-09-01 | |
| 发表期刊 | CHINESE JOURNAL OF CHEMISTRY
 |
| 卷号 | 26期号:9页码:1607-1610 |
| 文章类型 | Article |
| 摘要 | Two novel coordination polymers [Zn(pa)(vim)(2)](n) (1) and [Zn(pa)(eim)(2)](n) (2) (pa=phthalic acid dianion, vim=1-vinyl-1H-imidazole, eim=1-ethyl-1H-imidazole) have been synthesized and their structures characterized by X-ray single crystal diffractometry and elemental analysis. Both of the complexes consist of [Zn(L)21 (L=vim for 1; eim for 2) entities linked into polymeric zigzag chains along the crystallographic c-axis by bridging phthalate anions in the mu(2)-1,2 coordination mode. The coordination around each Zn(II) atom is tetrahedral. There are only van der Waals interactions between the chains in 1, while the three-dimensional network in 2 is assembled by C-H center dot center dot center dot O contacts. The electrochemical studies reveal that redoxes of Zn(2+)/Zn in complexes 1 and 2 are irreversible processes. |
| 关键词 | Phthalate Complex Zn(Ii) Carboxylate Crystal Structure Cyclic Voltammetry |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000259664300012 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.qdio.ac.cn/handle/337002/32624 |
| 专题 | 海洋环境腐蚀与生物污损重点实验室 |
| 作者单位 | 1.Qingdao Univ Sci & Technol, Key Lab Adv Mat, Qingdao 266042, Shandong, Peoples R China 2.Chinese Acad Sci, Inst Oceanol, Qingdao 266071, Shandong, Peoples R China |
| 第一作者单位 | 中国科学院海洋研究所 |
| 推荐引用方式 GB/T 7714 | Li Wei-Hua,Zhao Guang-Fa,Huang Zhao-Ge,et al. Synthesis, crystal structure and electrochemical studies of two novel Zn(II) complexes of phthalic acid and imidazole derivatives[J]. CHINESE JOURNAL OF CHEMISTRY,2008,26(9):1607-1610. |
| APA | Li Wei-Hua,Zhao Guang-Fa,Huang Zhao-Ge,Liu Fa-Qian,Ding Nai-Xu,&Liu Guang-Ye.(2008).Synthesis, crystal structure and electrochemical studies of two novel Zn(II) complexes of phthalic acid and imidazole derivatives.CHINESE JOURNAL OF CHEMISTRY,26(9),1607-1610. |
| MLA | Li Wei-Hua,et al."Synthesis, crystal structure and electrochemical studies of two novel Zn(II) complexes of phthalic acid and imidazole derivatives".CHINESE JOURNAL OF CHEMISTRY 26.9(2008):1607-1610. |
| 条目包含的文件 | ||||||
| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | ||
| Synthesis, crystal s（122KB） | 期刊论文 | 出版稿 | 限制开放 | ODC PDDL | 浏览 | |
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。
修改评论