Surface modification of ZrO2 nanoparticles with styrene coupling agent and its effect on the corrosion behaviour of epoxy coating
Zhao Xia1; Liu Shuan2; Wang Xiutong1; Hou Baorong1; Zhao, X (reprint author), Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China.
2014-09-01
发表期刊CHINESE JOURNAL OF OCEANOLOGY AND LIMNOLOGY
卷号32期号:5页码:1163-1171
文章类型Article
摘要The surface of ZrO2 nanoparticles was modified by styrene coupling grafting method to improve the dispersion and interaction of the nanoparticles with the epoxy coating in which the modified ZrO2 nanoparticles were used as an additive. The grafting performance and microstructure of the nano-ZrO2/epoxy coating were analyzed by Fourier transformation infrared spectroscopy, X-ray diffraction, and scanning electron microscopy. The corrosion behavior of the nano-ZrO2/epoxy coating on mild steel was evaluated in neutral 3.5 wt% NaCl solution using electrochemical impedance spectroscopy (EIS). Both the coating capacitance and coating resistance fitted by the equivalent circuit from EIS were used to evaluate the protective performance of the coating towards the mild steel. The results show a superior stability and efficient corrosion protection by the modified ZrO2 nanoparticles. The epoxy coating containing 2 wt% modified ZrO2 nanoparticles exhibited the best corrosion performance among all the coating specimens. This research may provide an insight into the protection of mild steel using modified epoxy coatings.
关键词Zro2 Nanoparticles Epoxy Coating Electrochemical Impedance Spectroscopy (Eis) Corrosion Behavior
学科领域Marine & Freshwater Biology ; Oceanography
DOI10.1007/s00343-014-3327-8
收录类别SCI
语种英语
WOS记录号WOS:000340879900021
引用统计
被引频次:25[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.qdio.ac.cn/handle/337002/23890
专题海洋环境腐蚀与生物污损重点实验室
海洋地质与环境重点实验室
通讯作者Zhao, X (reprint author), Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China.
作者单位1.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China
2.Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Zhejiang, Peoples R China
第一作者单位中国科学院海洋研究所
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GB/T 7714
Zhao Xia,Liu Shuan,Wang Xiutong,et al. Surface modification of ZrO2 nanoparticles with styrene coupling agent and its effect on the corrosion behaviour of epoxy coating[J]. CHINESE JOURNAL OF OCEANOLOGY AND LIMNOLOGY,2014,32(5):1163-1171.
APA Zhao Xia,Liu Shuan,Wang Xiutong,Hou Baorong,&Zhao, X .(2014).Surface modification of ZrO2 nanoparticles with styrene coupling agent and its effect on the corrosion behaviour of epoxy coating.CHINESE JOURNAL OF OCEANOLOGY AND LIMNOLOGY,32(5),1163-1171.
MLA Zhao Xia,et al."Surface modification of ZrO2 nanoparticles with styrene coupling agent and its effect on the corrosion behaviour of epoxy coating".CHINESE JOURNAL OF OCEANOLOGY AND LIMNOLOGY 32.5(2014):1163-1171.
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