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Effect of hydrogen treatment on the photoelectrochemical properties of quantum dots sensitized ZnO nanorod array | |
Bu, Yuyu; Chen, Zhuoyuan; Chen, ZY (reprint author), Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, 7 Nanhai Rd, Qingdao 266071, Peoples R China. | |
2014-12-25 | |
发表期刊 | JOURNAL OF POWER SOURCES |
卷号 | 272页码:647-653 |
文章类型 | Article |
摘要 | The hydrogenated ZnO nanorod array (NRA) was, for the first time, applied to the field of quantum dots (QDs) sensitized photoanodes. Hydrogen treatment at high temperature can significantly change the surface states of ZnO NRA. Partial oxygen atoms on the surface of ZnO are taken away by hydrogen, resulting in the formation of oxygen vacancies. The formation of oxygen vacancies significantly enhances the charge carrier density and the electron migration ability of ZnO NRA. Meanwhile, the energy barrier of the injection of the photoinduced electrons generated by CdS into ZnO NRA decreases due to the formation of doping energy levels under the conducting band of ZnO. Therefore, the photoelectrochemical performance of CdS QDs sensitized hydrogenated ZnO NRA is significantly improved. This work has potential significance in enhancing the performance of QDs sensitized solar cell as well as dye sensitized solar cell. (C) 2014 Elsevier B.V. All rights reserved. |
关键词 | Hydrogen Treatment Zno Nanorod Array Quantum Dots Photoelectrochemical Property Oxygen Vacancy |
学科领域 | Electrochemistry ; Energy & Fuels |
DOI | 10.1016/j.jpowsour.2014.08.127 |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000344208700080 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.qdio.ac.cn/handle/337002/23868 |
专题 | 海洋环境腐蚀与生物污损重点实验室 |
通讯作者 | Chen, ZY (reprint author), Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, 7 Nanhai Rd, Qingdao 266071, Peoples R China. |
作者单位 | Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China |
第一作者单位 | 中国科学院海洋研究所 |
推荐引用方式 GB/T 7714 | Bu, Yuyu,Chen, Zhuoyuan,Chen, ZY . Effect of hydrogen treatment on the photoelectrochemical properties of quantum dots sensitized ZnO nanorod array[J]. JOURNAL OF POWER SOURCES,2014,272:647-653. |
APA | Bu, Yuyu,Chen, Zhuoyuan,&Chen, ZY .(2014).Effect of hydrogen treatment on the photoelectrochemical properties of quantum dots sensitized ZnO nanorod array.JOURNAL OF POWER SOURCES,272,647-653. |
MLA | Bu, Yuyu,et al."Effect of hydrogen treatment on the photoelectrochemical properties of quantum dots sensitized ZnO nanorod array".JOURNAL OF POWER SOURCES 272(2014):647-653. |
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