Construction of a high-performance anti-corrosion epoxy coating in the presence of poly(aniline-co-pyrrole) nanospheres
Mirzaee, Majid1; Kianpour, Effat2; Rashidi, Alimorad3; Rahimi, Alireza4; Pourhashem, Sepideh5,6,7; Duan, Jizhou5,6,7; Iravani, Danial8; Gohari, Maryam Sirati3
2024
发表期刊REACTIVE & FUNCTIONAL POLYMERS
ISSN1381-5148
卷号194页码:15
通讯作者Rashidi, Alimorad([email protected])
摘要Since corrosion with its direct and indirect negative effects is a global issue, coatings are commonly used as a structural corrosion protection strategy. The reinforcement effects of Poly (aniline-co-pyrrole) (PACP) nanospheres on corrosion resistance of solvent-based epoxy coatings are investigated in this study. The corrosion behavior of mild steel substrates coated with epoxy containing different weight percents (0.25, 0.5, 0.75, and 1.0 wt%) of PACP nanospheres is investigated using electrochemical impedance spectroscopy (EIS) in a 3.5 wt% NaCl solution, while the fracture cross-section is studied by field emission scanning electron microscopy (FESEM). The incorporation of the PACP nanospheres in the polymer coatings considerably improves the protective performance of the epoxy coatings. The results of the EIS test shows that the highest corrosion resistance is for the EP-PACP- 0.75 wt% sample. In the first day of immersion, |Z|100kHz is equal to 5.2 x 1012 omega.cm2, which is much more than the pure epoxy sample (105 omega.cm2). After two months of immersion, the resistance reduction for the optimum sample is negligible and the amount of water uptake into the coating is the lowest. These findings demonstrate that the epoxy/PACP nanocomposite is superior when compared to the pure epoxy coating.
关键词Poly(aniline co -pyrrole) Nanospheres Epoxy Nanocomposite coatings Corrosion protection
DOI10.1016/j.reactfunctpolym.2023.105794
收录类别SCI
语种英语
资助项目Research Institute of Petroleum Industry (RIPI) , INSF's Project[99010368]; Ministry of Science and Technology Program for Young Foreign Talents[133137KYSB20200034]; CAS-VPST Silk Road Science Fund 2021; [QN2022055002L]
WOS研究方向Chemistry ; Engineering ; Polymer Science
WOS类目Chemistry, Applied ; Engineering, Chemical ; Polymer Science
WOS记录号WOS:001127619500001
出版者ELSEVIER
WOS关键词CORROSION PROTECTION PROPERTIES ; NANOCOMPOSITE COATINGS ; CONDUCTING POLYMERS ; STEEL ; POLYPYRROLE ; POLYANILINE ; INHIBITORS ; FILMS
引用统计
被引频次:4[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.qdio.ac.cn/handle/337002/184255
专题海洋环境腐蚀与生物污损重点实验室
通讯作者Rashidi, Alimorad
作者单位1.Niroo Res Inst, Nonmet Mat Res Grp, POB 14665517, Tehran, Iran
2.Univ Mazandaran, Fac Chem, Dept Phys Chem, POB 47416-9544, Babolsar, Iran
3.Res Inst Petr Ind RIPI, Nanotechnol Res Ctr, POB 14857-33111,West Entrance Blvd,Olymp Village, Tehran, Iran
4.Res Inst Petr Ind RIPI, Res & Dev Energy & Environm, POB 14857-33111,West Entrance Blvd,Olymp Village, Tehran, Iran
5.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, 7 Nanhai Rd, Qingdao 266071, Peoples R China
6.Pilot Natl Lab Marine Sci & Technol Qingdao, Open studio marine Corros & Protect, 1 Wenhai Rd, Qingdao 266237, Peoples R China
7.Chinese Acad Sci, Ctr Ocean Mega Sci, 7 Nanhai Rd, Qingdao 266071, Peoples R China
8.Univ Mashhad, Fac Engn, Chem Engn Dept, Mashhad, Iran
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GB/T 7714
Mirzaee, Majid,Kianpour, Effat,Rashidi, Alimorad,et al. Construction of a high-performance anti-corrosion epoxy coating in the presence of poly(aniline-co-pyrrole) nanospheres[J]. REACTIVE & FUNCTIONAL POLYMERS,2024,194:15.
APA Mirzaee, Majid.,Kianpour, Effat.,Rashidi, Alimorad.,Rahimi, Alireza.,Pourhashem, Sepideh.,...&Gohari, Maryam Sirati.(2024).Construction of a high-performance anti-corrosion epoxy coating in the presence of poly(aniline-co-pyrrole) nanospheres.REACTIVE & FUNCTIONAL POLYMERS,194,15.
MLA Mirzaee, Majid,et al."Construction of a high-performance anti-corrosion epoxy coating in the presence of poly(aniline-co-pyrrole) nanospheres".REACTIVE & FUNCTIONAL POLYMERS 194(2024):15.
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