Influence of Seawater Characteristics on Antibiotic Pollutant Removal via Fe(II)-Peroxymonosulfate-Modified Clay

doi:10.3390/w15091680

	Influence of Seawater Characteristics on Antibiotic Pollutant Removal via Fe(II)-Peroxymonosulfate-Modified Clay
	Jiang, Yuxin 1,2; Cao, Xihua2,3 ; Li, Fang 4; Song, Xiuxian2
	2023-04-26
发表期刊	WATER
卷号	15 期号:9 页码:11
通讯作者	Cao, Xihua([email protected])
摘要	Antibiotics have been identified as emerging pollutants, and they increasingly threaten the safety of mariculture; thus, effective treatment methods are urgently needed. In this study, Fe(II)-peroxymonosulfate-modified clay (Fe-PMS-MC), an effective mineral complex for harmful algal bloom control, was tested for sulfamethoxazole (SMX) removal from seawater. The results showed that SMX removal efficiency increased gradually from 42.3% to 100% in seawater in 6 h as the Fe-PMS-MC dose increased from 0.1 g/L to 1.0 g/L; this removal was more efficient than that in freshwater. Both an increase in temperature and the addition of inorganic anions such as Cl-, HCO3-, and SO42- improved the SMX removal efficiency; in contrast, there was no noticeable influence of a pH change from 3.0 to 9.0 or of Heterosigma akashiwo biomass addition from 10(3) cells/mL to 10(5) cells/mL. Oxidation was the main mechanism for the removal of SMX by Fe-PMS-MC treatment, and the mechanisms included radical oxidation and non-radical oxidation. PMS was the key component in Fe-PMS-MC for the production of radicals, which increased with temperature. Similarly, both radical oxidation and non-radical oxidation increased when PMS was attacked by Cl-, HCO3-, and SO42- in seawater.
关键词	antibiotic pollutant environmental factor modified clay oxidation seawater
DOI	10.3390/w15091680
收录类别	SCI
语种	英语
资助项目	China National Key R&D Program during the 14th Five-year Plan Period[2022YFC3105204]; National Natural Science Foundation of China[41976145]; Key Research Program of the Center for Ocean Mega-Science Chinese Academy of Sciences[COMS2020J02]; National Key Research and Development Program (Inter-Governmental Key Project for International Cooperation in Science and Technology Innovation)[SQ2022YFE010525]
WOS研究方向	Environmental Sciences & Ecology ; Water Resources
WOS类目	Environmental Sciences ; Water Resources
WOS记录号	WOS:000987168100001
出版者	MDPI
WOS关键词	ACTIVATED PERSULFATE OXIDATION ; PROROCENTRUM-DONGHAIENSE ; PEROXYMONOSULFATE ; DEGRADATION ; SULFAMETHOXAZOLE ; MECHANISMS ; WATER ; FLOCCULATION ; BLOOMS ; UV
引用统计	被引频次：1[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.qdio.ac.cn/handle/337002/182994
专题	海洋生态与环境科学重点实验室
通讯作者	Cao, Xihua
作者单位	1.Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Qingdao 266042, Peoples R China 2.Chinese Acad Sci, Inst Oceanol, CAS Key Lab Marine Ecol & Environm Sci, Qingdao 266071, Peoples R China 3.Guangxi Acad Sci, Guangxi Acad Marine Sci, Guangxi Key Lab Marine Environm Sci, Nanning 530007, Peoples R China 4.Qingdao Univ Sci & Technol, Coll Marine Sci & Biol Engn, Qingdao 266042, Peoples R China
第一作者单位	海洋生态与环境科学重点实验室
通讯作者单位	海洋生态与环境科学重点实验室
推荐引用方式 GB/T 7714	Jiang, Yuxin,Cao, Xihua,Li, Fang,et al. Influence of Seawater Characteristics on Antibiotic Pollutant Removal via Fe(II)-Peroxymonosulfate-Modified Clay[J]. WATER,2023,15(9):11.
APA	Jiang, Yuxin,Cao, Xihua,Li, Fang,&Song, Xiuxian.(2023).Influence of Seawater Characteristics on Antibiotic Pollutant Removal via Fe(II)-Peroxymonosulfate-Modified Clay.WATER,15(9),11.
MLA	Jiang, Yuxin,et al."Influence of Seawater Characteristics on Antibiotic Pollutant Removal via Fe(II)-Peroxymonosulfate-Modified Clay".WATER 15.9(2023):11.