Capsaicin-Modified Fluorosilicone Based Acrylate Coating for Marine Anti-Biofouling

doi:10.3390/coatings12070988

	Capsaicin-Modified Fluorosilicone Based Acrylate Coating for Marine Anti-Biofouling
	Liu, Jie 1,2,3; Sun, Jiawen2,3 ; Duan, Jizhou2,3 ; Dong, Xucheng2,3 ; Wang, Xinping 1; Liu, Chao 4; Hou, Baorong 2,3
	2022-07-01
发表期刊	COATINGS
卷号	12 期号:7 页码:11
通讯作者	Duan, Jizhou([email protected]) ; Wang, Xinping([email protected])
摘要	Capsaicin has been extensively studied for its excellent antifouling activity and very low environmental toxicity. However, mixing natural capsaicin with coatings can cause rapid capsaicin leakage, severely shortening its antifouling cycle. In this study, we describe the preparation and performance of a new capsaicin-modified marine antifouling organofluorosilicone, which is based on silicone and fluorine acrylate monomers covalently bound to an organic antimicrobial monomer, HMBA (N-(4-hydroxy-3-methoxybenzyl)-acrylamide) on a polymer network. The chemical grafting of HMBA into the polymer has improved the problem of short antifouling life of the coating due to antifouling agent leakage and the environmental pollution caused by the leakage. The study focused on the synthesis of pristine acrylate monomers with organic bioactive groups prepared from vanillin amine salts and their co-polymerization in the presence of distal acrylate oligomers. The resulting cross-linked films were characterized using infrared spectroscopy, contact angle, and adhesion analyses. The results indicate that the materials had good adhesion, low surface energy, and were resistant to prolonged immersion in water. The polyacrylate coating synthesized from acrylate exhibited antibacterial and anti-algae activity. Biological tests on the marine microorganisms, Pseudomonas species, Shewanella species, and Navicula incerta, revealed a 97%, 98%, and 99% reduction compared to the blank control group, respectively, indicating that the coating has strong anti-adhesive ability. This work is expected to develop a promising material for marine antifouling.
关键词	capsaicin fluorosilicone acrylic low surface energy marine anti-biofouling
DOI	10.3390/coatings12070988
收录类别	SCI
语种	英语
资助项目	Basic Frontier Science Research Program of Chinese Academy of Sciences[ZDBS-LY-DQC025]; National Natural Science Foundation of China[41706080]; Strategic Leading Science & Technology Programme of the Chinese Academy of Sciences[XDA13040403]; National College Students' innovation and entrepreneurship training program[202110426072]; Shandong Key Laboratory of Corrosion Science; Talent Foundation; Ministry Co-construction Collaborative Innovation Center of Eco-chemical Engineering[STHGYX2202]
WOS研究方向	Materials Science ; Physics
WOS类目	Materials Science, Multidisciplinary ; Materials Science, Coatings & Films ; Physics, Applied
WOS记录号	WOS:000831711800001
出版者	MDPI
引用统计	被引频次：3[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.qdio.ac.cn/handle/337002/179836
专题	海洋环境腐蚀与生物污损重点实验室
通讯作者	Duan, Jizhou; Wang, Xinping
作者单位	1.Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, 53 Zhengzhou Rd, Qingdao 266042, Peoples R China 2.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, 7 Nanhai Rd, Qingdao 266071, Peoples R China 3.Pilot Natl Lab Marine Sci & Technol Qingdao, Open Studio Marine Corros & Protect, 1 Wenhai Middle Rd, Qingdao 266237, Peoples R China 4.Hunan Agr Univ, Coll Resources & Environm, 1 Nongda Rd, Changsha 410128, Peoples R China
第一作者单位	中国科学院海洋研究所
通讯作者单位	中国科学院海洋研究所
推荐引用方式 GB/T 7714	Liu, Jie,Sun, Jiawen,Duan, Jizhou,et al. Capsaicin-Modified Fluorosilicone Based Acrylate Coating for Marine Anti-Biofouling[J]. COATINGS,2022,12(7):11.
APA	Liu, Jie.,Sun, Jiawen.,Duan, Jizhou.,Dong, Xucheng.,Wang, Xinping.,...&Hou, Baorong.(2022).Capsaicin-Modified Fluorosilicone Based Acrylate Coating for Marine Anti-Biofouling.COATINGS,12(7),11.
MLA	Liu, Jie,et al."Capsaicin-Modified Fluorosilicone Based Acrylate Coating for Marine Anti-Biofouling".COATINGS 12.7(2022):11.