Distinctive roles of graphene oxide, ZnO quantum dots, and their nanohybrids in anti-corrosion and anti-fouling performance of waterborne epoxy coatings

doi:10.1016/j.cej.2022.135765

	Distinctive roles of graphene oxide, ZnO quantum dots, and their nanohybrids in anti-corrosion and anti-fouling performance of waterborne epoxy coatings
	Zhou, Ziyang 1,2,3; Pourhashem, Sepideh 1,3,4; Wang, Zhengquan1,2,3 ; Duan, Jizhou1,3,4 ; Zhang, Ruiyong 1,3,4; Hou, Baorong 1,3,4
	2022-07-01
发表期刊	CHEMICAL ENGINEERING JOURNAL
ISSN	1385-8947
卷号	439 页码:13
通讯作者	Duan, Jizhou([email protected])
摘要	In this research, the amino-silane functionalized ZnO quantum dots (F-ZnO QDs), graphene oxide (F-GO), and their nanohybrids (F-GO@ZnO QDs) are used as effective nanofillers to improve the anti-corrosion and antifouling properties of waterborne epoxy coatings. The synthesized nanomaterials before and after silane functionalization are characterized by X-ray diffraction, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and transmission electron microscopy. Then, the nanocomposite waterborne epoxy coatings loaded with 0.1 wt% F-ZnO QDs, F-GO, and F-GO@ZnO QDs are prepared through solution mixing method. The effects of different nanofillers on the surface roughness, water contact angle, pull-off adhesion strength, fracture surface, and corrosion resistance of the nanocomposite coatings are considered. The results reveal that the uniformly dispersed F-GO@ZnO QDs in the fracture surface of the coating could provide the highest barrier and corrosion resistance on the steel substrates. Meanwhile, the nanocomposite coatings have higher water contact angle and higher adhesion strength to the substrates. The anti-bacterial and anti-fouling properties of the nanocomposite coatings have also been confirmed. The multifunctional performance of the epoxy/F-GO@ZnO QDs is assigned to the synergy effect between the GO, ZnO QDs, and amino-silane; exhibiting the importance of the nanohybrids to combine the advantages of different nanomaterials in one coating system.
关键词	Waterborne epoxy coating Graphene oxide ZnO quantum dots Nanohybrids Anti-corrosion and anti-fouling properties
DOI	10.1016/j.cej.2022.135765
收录类别	SCI
语种	英语
资助项目	CAS-VPST Silk Road Science Fund[133137KYSB20200034]; Applied Basic Research Programs of Qingdao[E1KY12106N]; [2021 (133137KYSB20200034)]
WOS研究方向	Engineering
WOS类目	Engineering, Environmental ; Engineering, Chemical
WOS记录号	WOS:000783193800003
出版者	ELSEVIER SCIENCE SA
引用统计	被引频次：60[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.qdio.ac.cn/handle/337002/178733
专题	海洋环境腐蚀与生物污损重点实验室
通讯作者	Duan, Jizhou
作者单位	1.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, 7 Nanhai Rd, Qingdao 266071, Peoples R China 2.Univ Chinese Acad Sci, 19 Jia Yuquan Rd, Beijing 100049, Peoples R China 3.Pilot Natl Lab Marine Sci & Technol Qingdao, Open Studio Marine Corros & Protect, 1 Wenhai Rd, Qingdao 266237, Peoples R China 4.Chinese Acad Sci, Ctr Ocean Mega Sci, 7 Nanhai Rd, Qingdao 266071, Peoples R China
第一作者单位	中国科学院海洋研究所
通讯作者单位	中国科学院海洋研究所
推荐引用方式 GB/T 7714	Zhou, Ziyang,Pourhashem, Sepideh,Wang, Zhengquan,et al. Distinctive roles of graphene oxide, ZnO quantum dots, and their nanohybrids in anti-corrosion and anti-fouling performance of waterborne epoxy coatings[J]. CHEMICAL ENGINEERING JOURNAL,2022,439:13.
APA	Zhou, Ziyang,Pourhashem, Sepideh,Wang, Zhengquan,Duan, Jizhou,Zhang, Ruiyong,&Hou, Baorong.(2022).Distinctive roles of graphene oxide, ZnO quantum dots, and their nanohybrids in anti-corrosion and anti-fouling performance of waterborne epoxy coatings.CHEMICAL ENGINEERING JOURNAL,439,13.
MLA	Zhou, Ziyang,et al."Distinctive roles of graphene oxide, ZnO quantum dots, and their nanohybrids in anti-corrosion and anti-fouling performance of waterborne epoxy coatings".CHEMICAL ENGINEERING JOURNAL 439(2022):13.

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