A Piecewise Model for In Situ Raman Measurement of the Chlorinity of Deep-Sea High-Temperature Hydrothermal Fluids

doi:10.1177/0003702821999114

IOCAS-IR > 海洋地质与环境重点实验室

	A Piecewise Model for In Situ Raman Measurement of the Chlorinity of Deep-Sea High-Temperature Hydrothermal Fluids
	Ge, Meng1,2,3,4,5 ; Li, Lianfu1,2,3,4,5 ; Zhang, Xin 1,2,3,4,5; Luan, Zhendong 1,2,3,5; Du, Zengfeng 1,2,5; Xi, Shichuan1,2,4,5 ; Yan, Jun 1,2,5
	2021-03-09
发表期刊	APPLIED SPECTROSCOPY
ISSN	0003-7028
页码	11
通讯作者	Zhang, Xin([email protected])
摘要	The chlorinity of deep-sea hydrothermal fluids, representing one of the crucial deep-sea hydrothermal indicators, indicates the degree of deep phase separation of hydrothermal fluids and water/rock reactions. However, accurately measuring the chlorinity of high-temperature hydrothermal fluids is still a significant challenge. In this paper, a piecewise chlorinity model to measure the chlorinity of high-temperature hydrothermal fluids was developed based on the OH stretching band of water, exhibiting an accuracy of 96.20%. The peak position, peak area ratio, and F value were selected to establish the chlorinity piecewise calibration model within the temperature ranges of 0-50 celcius, 50-200 celcius, and 200-300 celcius. Compared with that of the chlorinity calibration model built based on a single parameter, the accuracy of this piecewise model increased by approximately 4.83-12.33%. This chlorinity calibration model was applied to determine the concentrations of Cl for high-temperature hydrothermal fluids in the Okinawa Trough hydrothermal field.
关键词	In situ hydrothermal fluids Raman spectroscopy chlorinity OH stretching band
DOI	10.1177/0003702821999114
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[41822604]; National Natural Science Foundation of China[92058206]; Strategic Priority Research Program, CAS[XDA22050102]; Strategic Priority Research Program, CAS[XDA19060402]; Laboratory for Marine Geology, Qingdao Pilot National Laboratory for Marine Science and Technology[MGQNLM-TD201904]; Young Taishan Scholars Program[tsqn201909158]
WOS研究方向	Instruments & Instrumentation ; Spectroscopy
WOS类目	Instruments & Instrumentation ; Spectroscopy
WOS记录号	WOS:000680123700001
出版者	SAGE PUBLICATIONS INC
引用统计	被引频次：1[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.qdio.ac.cn/handle/337002/175960
专题	海洋地质与环境重点实验室
通讯作者	Zhang, Xin
作者单位	1.Chinese Acad Sci, Inst Oceanol, CAS Key Lab Marine Geol & Environm, Qingdao, Peoples R China 2.Chinese Acad Sci, Inst Oceanol, Ctr Deep Sea Res, Qingdao, Peoples R China 3.Qingdao Natl Lab Marine Sci & Technol, Lab Marine Geol, Qingdao, Peoples R China 4.Univ Chinese Acad Sci, Coll Earth & Planetary Sci, Beijing, Peoples R China 5.Chinese Acad Sci, Ctr Ocean Mega Sci, Qingdao, Peoples R China
推荐引用方式 GB/T 7714	Ge, Meng,Li, Lianfu,Zhang, Xin,et al. A Piecewise Model for In Situ Raman Measurement of the Chlorinity of Deep-Sea High-Temperature Hydrothermal Fluids[J]. APPLIED SPECTROSCOPY,2021:11.
APA	Ge, Meng.,Li, Lianfu.,Zhang, Xin.,Luan, Zhendong.,Du, Zengfeng.,...&Yan, Jun.(2021).A Piecewise Model for In Situ Raman Measurement of the Chlorinity of Deep-Sea High-Temperature Hydrothermal Fluids.APPLIED SPECTROSCOPY,11.
MLA	Ge, Meng,et al."A Piecewise Model for In Situ Raman Measurement of the Chlorinity of Deep-Sea High-Temperature Hydrothermal Fluids".APPLIED SPECTROSCOPY (2021):11.