Study on the corrosion behavior of copper coupled with TiO2 with different crystal structures

doi:10.1016/j.corsci.2021.109352

IOCAS-IR

	Study on the corrosion behavior of copper coupled with TiO2 with different crystal structures
	Zhang, Xinyu 1; Li, Sijia 1; Sun, Wen 1; Wang, Lida 1; Wang, Jing 2; Liu, Guichang 1
	2021-05-01
发表期刊	CORROSION SCIENCE
ISSN	0010-938X
卷号	183 页码:10
摘要	The influences of semi-conductive TiO2 with different crystal structures on the initial corrosion behavior of copper in dark conditions were investigated. Results showed that anatase TiO2 showed "corrosion-promotion activity" to copper, while rutile TiO2 did not. It is revealed that the "corrosion-promotion activity" is associated with TiO2 crystal structure and mainly dominated by the work function of TiO2. When the work function of n-type TiO2 is higher than that of copper, electrons are inclined to transfer from copper to TiO2. In addition, higher electrical conductivity and oxygen reduction reaction activity of TiO2 facilitate the electron consumption at the TiO2/electrolyte interface.
关键词	TiO2 Copper Work function Oxygen reduction reaction Corrosion-promotion activity
DOI	10.1016/j.corsci.2021.109352
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[21703026]; National Natural Science Foundation of China[51671047]; National Natural Science Foundation of China[21978036]; National Natural Science Foundation of China[21403030]; Key R&D Project of Ningxia Hui Autonomous Region[2019BFG02016]; China Postdoctoral Science Foundation[2017M610177]; China Postdoctoral Science Foundation[2018T110222]; Research Fund of Open Studio for Marine Corrosion and Protection and Pilot National Laboratory for Marine Science and Technology (Qingdao)[HYFSKF-201804]; Fundamental Research Funds for the Central Universities[DUT19RC(4)003]
WOS研究方向	Materials Science ; Metallurgy & Metallurgical Engineering
WOS类目	Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS记录号	WOS:000632809000001
出版者	PERGAMON-ELSEVIER SCIENCE LTD
引用统计	被引频次：14[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
版本	出版稿
条目标识符	http://ir.qdio.ac.cn/handle/337002/170393
专题	中国科学院海洋研究所
通讯作者	Wang, Lida; Liu, Guichang
作者单位	1.Dalian Univ Technol, Sch Chem Engn, Dalian 116024, Peoples R China 2.Chinese Acad Sci, Inst Oceanol, Qingdao 266071, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Xinyu,Li, Sijia,Sun, Wen,et al. Study on the corrosion behavior of copper coupled with TiO2 with different crystal structures[J]. CORROSION SCIENCE,2021,183:10.
APA	Zhang, Xinyu,Li, Sijia,Sun, Wen,Wang, Lida,Wang, Jing,&Liu, Guichang.(2021).Study on the corrosion behavior of copper coupled with TiO2 with different crystal structures.CORROSION SCIENCE,183,10.
MLA	Zhang, Xinyu,et al."Study on the corrosion behavior of copper coupled with TiO2 with different crystal structures".CORROSION SCIENCE 183(2021):10.

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