| In situ Raman quantitative detection of methane concentrations in deep-sea high-temperature hydrothermal vent fluids | |
Li, Lianfu1,2,3,4 ; Zhang, Xin1,2,3,4,5; Luan, Zhendong1,2,3; Du, Zengfeng1,2; Xi, Shichuan1,2,4; Wang, Bing1,2,4; Cao, Lei1,2; Lian, Chao1,2; Yan, Jun1,2
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| 2020-09-02 | |
| 发表期刊 | JOURNAL OF RAMAN SPECTROSCOPY
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| ISSN | 0377-0486 |
| 页码 | 10 |
| 通讯作者 | Zhang, Xin([email protected]) |
| 摘要 | Raman spectroscopy is an ideal approach for measuring methane concentrations in deep-sea high-temperature hydrothermal vent fluids due to its advantages of being nondestructive and noninvasive and not requiring sample pretreatment. However, no application of Raman spectroscopy in the measurement of hydrothermal methane has yet been reported because of the lack of Raman quantitative calibration models for CH(4)suitable for hydrothermal fluid detection and available for deep-sea in situ Raman experiments. In this study, a new Raman quantitative calibration model suitable for hydrothermal fluid detection was established with the linear equationACH4/AH2O= (2.61E-3 +/- 8.52E-6) xCCH4, whereACH4/AH2Ois the peak area ratio of CH(4)and H2O andCCH4is the concentration of dissolved CH(4)in mmol/kg. In situ Raman spectra of deep-sea hydrothermal fluids were acquired using an adapted deep-sea in situ Raman spectrometer, Raman insertion probe (RiP) system, and then the methane concentrations were determined based on the quantitative calibration model for CH4. The concentrations of methane measured by RiP are approximately 1.5-4.0 times higher than those derived from the gas-tight samples collected simultaneously at the same vents, which indicates that the amount of methane released from the hydrothermal system has probably been underestimated. |
| 关键词 | dissolved CH4 hydrothermal vent fluid in situ quantitative analysis Raman spectroscopy |
| DOI | 10.1002/jrs.5981 |
| 收录类别 | SCI |
| 语种 | 英语 |
| 资助项目 | National Natural Science Foundation of China[41822604]; National Natural Science Foundation of China[41576104]; Strategic Priority Research Program, CAS[XDA22050102]; National Key R&D Program of China[2016YFC0302103]; Key Research Program of Frontier Sciences, CAS[QYZDB-SSW-DQC004]; NSFC-Shandong Joint Fund for Marine Science Research Centers[U1606401]; Young Taishan Scholars Program[tsqn201909158]; Laboratory for Marine Geology, Qingdao Pilot National Laboratory for Marine Science and Technology[MGQNLM-TD201904] |
| WOS研究方向 | Spectroscopy |
| WOS类目 | Spectroscopy |
| WOS记录号 | WOS:000567259500001 |
| 出版者 | WILEY |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.qdio.ac.cn/handle/337002/168763 |
| 专题 | 海洋地质与环境重点实验室 |
| 通讯作者 | Zhang, Xin |
| 作者单位 | 1.Chinese Acad Sci, CAS Key Lab Marine Geol & Environm, Inst Oceanol, Qingdao 266071, Peoples R China 2.Chinese Acad Sci, Ctr Deep Sea Res, Inst Oceanol, Qingdao 266071, Peoples R China 3.Pilot Qingdao Natl Lab Marine Sci & Technol Qingd, Lab Marine Geol, Qingdao, Peoples R China 4.Univ Chinese Acad Sci, Beijing, Peoples R China 5.Chinese Acad Sci, Ctr Ocean Megasci, Qingdao, Peoples R China |
| 第一作者单位 | 中国科学院海洋研究所 |
| 通讯作者单位 | 中国科学院海洋研究所; 中国科学院海洋大科学研究中心 |
| 推荐引用方式 GB/T 7714 | Li, Lianfu,Zhang, Xin,Luan, Zhendong,et al. In situ Raman quantitative detection of methane concentrations in deep-sea high-temperature hydrothermal vent fluids[J]. JOURNAL OF RAMAN SPECTROSCOPY,2020:10. |
| APA | Li, Lianfu.,Zhang, Xin.,Luan, Zhendong.,Du, Zengfeng.,Xi, Shichuan.,...&Yan, Jun.(2020).In situ Raman quantitative detection of methane concentrations in deep-sea high-temperature hydrothermal vent fluids.JOURNAL OF RAMAN SPECTROSCOPY,10. |
| MLA | Li, Lianfu,et al."In situ Raman quantitative detection of methane concentrations in deep-sea high-temperature hydrothermal vent fluids".JOURNAL OF RAMAN SPECTROSCOPY (2020):10. |
| 条目包含的文件 | ||||||
| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | ||
| jrs.5981.pdf（18493KB） | 期刊论文 | 出版稿 | 限制开放 | CC BY-NC-SA | 浏览 | |
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