Adsorption characteristics of chitooligosaccharides onto activated charcoal in aqueous solutions

doi:10.1007/s00343-019-8327-2

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	Adsorption characteristics of chitooligosaccharides onto activated charcoal in aqueous solutions
	Yu Yu 1; Li Kecheng 2,3
	2019-10-19
发表期刊	JOURNAL OF OCEANOLOGY AND LIMNOLOGY
ISSN	2096-5508
页码	9
通讯作者	Li Kecheng([email protected])
摘要	To investigate the adsorption characteristics of chitooligosaccharides in solution onto activated charcoal, we studied the optimal adsorption conditions and the adsorption mechanisms of the chitooligosaccharides onto activated charcoal, which will greatly promote the application of activated charcoal in the chitooligosaccharides separation and purification. We studied the effects of particle size of activated charcoal, pH of solution, contact time, temperature, and initial concentration of chitooligosaccharides on the adsorption behavior in batch mode experiments. Activated charcoal in fine particle size showed a high uptake of chitooligosaccharides. Weak alkaline solution (pH 8-9) was the most favorable to the adsorption. The adsorption equilibrium after 60 min was established, which followed a pseudo-second-order kinetic model. The adsorption capacity (Q(max)) reached 0.195 g/g (chitooligosaccharides/activated charcoal) at 298 K. The adsorption was temperature-insensitive, and the adsorption isotherms could be best described by the Langmuir equation. Chitooligosaccharides adsorbed on activated charcoal could be desorbed in 50% ethanol solution in combination with an acidic condition (pH 2), reaching desorption efficiency of 96.0%. These findings are of great significance for the production and purification of amino oligosaccharides including chitooligosaccharides using activated charcoal.
关键词	chitooligosaccharide adsorption activated charcoal kinetics isotherm
DOI	10.1007/s00343-019-8327-2
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[41976096]###3313; National Key R&D Program of China[2018YFC0311305]###203; Open Fund of CAS Key Laboratory of Marine Ecology and Environmental Sciences, Institute of Oceanology, Chinese Academy of Sciences[KLMEES201805]###3314; Talent Research Foundation of Qingdao Agricultural University[1114347]###3315; National Natural Science Foundation of China[41976096]; National Key R&D Program of China[2018YFC0311305]; Open Fund of CAS Key Laboratory of Marine Ecology and Environmental Sciences, Institute of Oceanology, Chinese Academy of Sciences[KLMEES201805]; Talent Research Foundation of Qingdao Agricultural University[1114347]
WOS研究方向	Marine & Freshwater Biology ; Oceanography
WOS类目	Limnology ; Oceanography
WOS记录号	WOS:000491530200001
出版者	SCIENCE PRESS
引用统计	被引频次：5[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.qdio.ac.cn/handle/337002/163432
专题	实验海洋生物学重点实验室
通讯作者	Li Kecheng
作者单位	1.Qingdao Agr Univ, Marine Sci & Engn Coll, Qingdao 266109, Shandong, Peoples R China 2.Chinese Acad Sci, Ctr Ocean Megasci, Inst Oceanol, Key Lab Expt Marine Biol, Qingdao 266071, Shandong, Peoples R China 3.Qingdao Natl Lab Marine Sci & Technol, Lab Marine Drugs & Bioprod, Qingdao 266237, Shandong, Peoples R China
通讯作者单位	中国科学院海洋大科学研究中心
推荐引用方式 GB/T 7714	Yu Yu,Li Kecheng. Adsorption characteristics of chitooligosaccharides onto activated charcoal in aqueous solutions[J]. JOURNAL OF OCEANOLOGY AND LIMNOLOGY,2019:9.
APA	Yu Yu,&Li Kecheng.(2019).Adsorption characteristics of chitooligosaccharides onto activated charcoal in aqueous solutions.JOURNAL OF OCEANOLOGY AND LIMNOLOGY,9.
MLA	Yu Yu,et al."Adsorption characteristics of chitooligosaccharides onto activated charcoal in aqueous solutions".JOURNAL OF OCEANOLOGY AND LIMNOLOGY (2019):9.

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