Institutional Repository of Key Laboratory of Marine Environmental Corrosion and Bio-fouling, IOCAS
Fluorometric detection of sulfate-reducing bacteria via the aggregation-induced emission of glutathione-gold(I) complexes | |
Zheng, Laibao1,2,3,4; Ye, Xiangyi1,2,3,4; Qi, Peng1,2,4; Zhang, Dun1,2,4; Sun, Yan1,2,4 | |
2019-06-01 | |
发表期刊 | MICROCHIMICA ACTA |
ISSN | 0026-3672 |
卷号 | 186期号:6页码:8 |
通讯作者 | Qi, Peng([email protected]) ; Zhang, Dun([email protected]) |
摘要 | It is reported that gold(I)-thiolate complexes can display aggregation-induced emission (AIE) similar to organic fluorogens. On addition of lead(II) to glutathione-gold(I) complexes, a supermolecular structure of type GSH-Au(I)-Pb(II) is formed through strong coordination between Pb(II) and GSH. Its fluorescence is quenched by sulfide due to the formation of PbS which destroys the GSH-Au(I)-Pb(II) complex. The finding was used to design a method for fluorometric detection of sulfate-reducing bacteria (SRB) which produce sulfide. The time needed to reduce fluorescence to 10% of its initial intensity linearly dependent on the logarithm of the SRB concentrations in the ranging from 10 to 1x10<^>7 cfu mL(-1). The assay time is also reduced down to 4 days even if the SRB concentration is as low as 10 cfu mL(-1). |
关键词 | Aggregation-induced-emission Gold(I)-thiolate complexes Sulfate-reducing bacteria detection Fluorometric detection Metal-thiolate complexes Sulfide detection Bacteria detection |
DOI | 10.1007/s00604-019-3427-4 |
收录类别 | SCI |
语种 | 英语 |
资助项目 | National Natural Science Foundation of China[41876101]###507; Young Elite Scientists Sponsorship Program by CAST[2018QNRC001]###508; Applied Basic Research Program of Nantong[GY12017005]###509; AoShan Talent Program###510; Qingdao National Laboratory for Marine Science and Technology[2017ASTCP-ES02]###181; National Natural Science Foundation of China[41876101]; Young Elite Scientists Sponsorship Program by CAST[2018QNRC001]; Applied Basic Research Program of Nantong[GY12017005]; AoShan Talent Program; Qingdao National Laboratory for Marine Science and Technology[2017ASTCP-ES02] |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Analytical |
WOS记录号 | WOS:000469237000002 |
出版者 | SPRINGER WIEN |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.qdio.ac.cn/handle/337002/161581 |
专题 | 海洋环境腐蚀与生物污损重点实验室 |
通讯作者 | Qi, Peng; Zhang, Dun |
作者单位 | 1.Chinese Acad Sci, CAS Key Lab Marine Environm Corros & Biofouling, Inst Oceanol, 7 Nanhai Rd, Qingdao 266071, Shandong, Peoples R China 2.Qingdao Natl Lab Marine Sci & Technol, Open Studio Marine Corros & Protect, 1 Wenhai Rd, Qingdao 266237, Shandong, Peoples R China 3.Univ Chinese Acad Sci, 19 Jia Yuquan Rd, Beijing 100039, Peoples R China 4.Chinese Acad Sci, Ctr Ocean Mega Sci, 7 Nanhai Rd, Qingdao 266071, Shandong, Peoples R China |
第一作者单位 | 中国科学院海洋研究所 |
通讯作者单位 | 中国科学院海洋研究所 |
推荐引用方式 GB/T 7714 | Zheng, Laibao,Ye, Xiangyi,Qi, Peng,et al. Fluorometric detection of sulfate-reducing bacteria via the aggregation-induced emission of glutathione-gold(I) complexes[J]. MICROCHIMICA ACTA,2019,186(6):8. |
APA | Zheng, Laibao,Ye, Xiangyi,Qi, Peng,Zhang, Dun,&Sun, Yan.(2019).Fluorometric detection of sulfate-reducing bacteria via the aggregation-induced emission of glutathione-gold(I) complexes.MICROCHIMICA ACTA,186(6),8. |
MLA | Zheng, Laibao,et al."Fluorometric detection of sulfate-reducing bacteria via the aggregation-induced emission of glutathione-gold(I) complexes".MICROCHIMICA ACTA 186.6(2019):8. |
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