Institutional Repository of Key Laboratory of Marine Environmental Corrosion and Bio-fouling, IOCAS
| Study on the Mechanism of the Photoelectrochemical Effect on the Initial NaCl-Induced Atmospheric Corrosion Process of Pure Copper Exposed in Humidified Pure Air | |
Li, Hengte1,2 ; Chen, Zhuoyuan1,2; Liu, Xingchen1; Hou, Jian2; Sun, Mingxian2; Zeng, Rongchang3
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| 2018 | |
| 发表期刊 | JOURNAL OF THE ELECTROCHEMICAL SOCIETY
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| ISSN | 0013-4651 |
| 卷号 | 165期号:10页码:C608-C617 |
| 通讯作者 | Chen, Zhuoyuan([email protected]) |
| 摘要 | The mechanism of the photoelectrochemical (PEC) effect of the corrosion products with semiconductor properties on the initial NaCl-induced atmospheric corrosion of pure copper was studied in this work. The effect of UV illumination on the initial NaCl-induced atmospheric corrosion of pure copper was quantitatively studied using microgravimetry. Fourier transform infrared spectroscopy, X-ray diffraction and scanning electron microscopy were used to identify the corrosion products and corrosion morphologies. Mott-Schottky methods were used to characterize the semiconductor type of the corrosion products. The photoinduced variations of the open circuit potentials, current densities, i-V curves and the polarization curves were used to analyze the PEC effect of the corrosion products with semiconductor properties on the corrosion of copper. UV illumination significantly increased the NaCl-induced atmospheric corrosion rate of copper. The photoinduced electrons did not transfer to the copper substrate, on the contrary, the photogenerated holes captured the electrons from the copper substrate, thus accelerating the atmospheric corrosion process of pure copper. The detailed influencing mechanism of the PEC effect on the NaCl-induced atmospheric corrosion of copper was suggested in this paper. (C) 2018 The Electrochemical Society. |
| DOI | 10.1149/2.0771810jes |
| 收录类别 | SCI |
| 语种 | 英语 |
| 资助项目 | National Natural Science Foundation of China[41576114]###32; Qingdao Innovative Leading Talent Foundation[15-10-3-15-(39)-zch]###33; Qingdao Science and Technology Achievement Transformation Guidance Plan (Applied Basic Research)[14-2-4-4-jch]###34; State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute, China[614290101011703]###28; National Natural Science Foundation of China[41576114]; Qingdao Innovative Leading Talent Foundation[15-10-3-15-(39)-zch]; Qingdao Science and Technology Achievement Transformation Guidance Plan (Applied Basic Research)[14-2-4-4-jch]; State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute, China[614290101011703] |
| WOS研究方向 | Electrochemistry ; Materials Science |
| WOS类目 | Electrochemistry ; Materials Science, Coatings & Films |
| WOS记录号 | WOS:000441061800063 |
| 出版者 | ELECTROCHEMICAL SOC INC |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.qdio.ac.cn/handle/337002/159699 |
| 专题 | 海洋环境腐蚀与生物污损重点实验室 |
| 通讯作者 | Chen, Zhuoyuan |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Marine Environm Corros & Biofouling, Inst Oceanol, Qingdao 266071, Peoples R China 2.Luoyang Ship Mat Res Inst, State Key Lab Marine Corros & Protect, Qingdao 266237, Peoples R China 3.Shandong Univ Sci & Technol, Coll Mat Sci & Engn, Qingdao 266590, Peoples R China |
| 第一作者单位 | 中国科学院海洋研究所 |
| 通讯作者单位 | 中国科学院海洋研究所 |
| 推荐引用方式 GB/T 7714 | Li, Hengte,Chen, Zhuoyuan,Liu, Xingchen,et al. Study on the Mechanism of the Photoelectrochemical Effect on the Initial NaCl-Induced Atmospheric Corrosion Process of Pure Copper Exposed in Humidified Pure Air[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY,2018,165(10):C608-C617. |
| APA | Li, Hengte,Chen, Zhuoyuan,Liu, Xingchen,Hou, Jian,Sun, Mingxian,&Zeng, Rongchang.(2018).Study on the Mechanism of the Photoelectrochemical Effect on the Initial NaCl-Induced Atmospheric Corrosion Process of Pure Copper Exposed in Humidified Pure Air.JOURNAL OF THE ELECTROCHEMICAL SOCIETY,165(10),C608-C617. |
| MLA | Li, Hengte,et al."Study on the Mechanism of the Photoelectrochemical Effect on the Initial NaCl-Induced Atmospheric Corrosion Process of Pure Copper Exposed in Humidified Pure Air".JOURNAL OF THE ELECTROCHEMICAL SOCIETY 165.10(2018):C608-C617. |
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| Study on the Mechani（1653KB） | 期刊论文 | 出版稿 | 限制开放 | CC BY-NC-SA | 浏览 | |
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