Institutional Repository of Key Laboratory of Marine Environmental Corrosion and Bio-fouling, IOCAS
| Ultrasound-assisted synthesis of wear-resistant Zn-Ferrocene composite coatings with high anticorrosive properties in alkaline environments | |
Zhai, Xiaofan1,2,5 ; Li, Ke1,2,3; Guan, Fang1,2,5; Wang, Nan1,2,3; Agievich, Maria4; Duan, Jizhou1,2,5; Hou, Baorong1,2,5
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| 2018-12-25 | |
| 发表期刊 | SURFACE & COATINGS TECHNOLOGY
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| ISSN | 0257-8972 |
| 卷号 | 356页码:19-28 |
| 通讯作者 | Zhai, Xiaofan([email protected]) ; Duan, Jizhou([email protected]) |
| 摘要 | Zn coatings are widely applied due to their low cost and negative potential in steel construction and reinforcing steel bars in concretes. However, Zn coatings have been found to perform unsatisfactorily in moist and alkaline environments. In the aqueous alkali environments that inevitably form when concretes fail, galvanized reinforcing steel bars have extremely low corrosion resistance and, consequently, are subject to corrosion. Facing these problems, various additives, including organic and inorganic compounds, have been introduced into Zn coatings to obtain enhanced corrosion resistance, with fewer experiments focusing on organometallic compound composited coatings. As a typical organometallic compound, ferrocene possesses high resistance to corrosive media, such as acids and alkalis. This makes ferrocene an extremely appropriate additive for composite Zn coatings. In this study, Zn-Ferrocene composite coatings were synthesized via electrodeposition with ultrasound assistance. Ferrocene was successfully incorporated using electrochemical control, with a maximum ferrocene content determined to be 19.4% of the C present in the composite coating. The surface morphologies and crystalline structures of the resultant coatings were significantly altered to thin, flake-like hexagonal crystals, a characteristic that was associated with the electrodepositing atomic matrix. The addition of ferrocene greatly improved the wear resistance of the composite coatings, with a 25% mass loss of pure zinc within the coating. The best properties were obtained at an ultrasound assistance level of 15 W. In addition, the corrosion mechanism of the composite coatings was studied at the molecular level. It was found that the corrosion resistance of the composite coatings in alkaline solutions was noticeably enhanced, with an R at value doubled showing the charge transfer process was inhibited. These results indicate that ultrasound-assisted Zn-Ferrocene composite coatings hold much promise for their potential use in reinforced steel bars in concretes and other abrasive environments. |
| 关键词 | Zn-Ferrocene Composite coating Ultrasound-assisted electrodepositing Wear resistance Corrosion behavior |
| DOI | 10.1016/j.surfcoat.2018.09.047 |
| 收录类别 | SCI |
| 语种 | 英语 |
| 资助项目 | National Natural Science Foundation of China[41811530090]###955; National Natural Science Foundation of China[41706080]###956; Key Research and Development Program of Shandong Province[2018GHY115029]###957; National Natural Science Foundation of China[41811530090]; National Natural Science Foundation of China[41706080]; Key Research and Development Program of Shandong Province[2018GHY115029] |
| WOS研究方向 | Materials Science ; Physics |
| WOS类目 | Materials Science, Coatings & Films ; Physics, Applied |
| WOS记录号 | WOS:000449131100003 |
| 出版者 | ELSEVIER SCIENCE SA |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.qdio.ac.cn/handle/337002/156577 |
| 专题 | 海洋环境腐蚀与生物污损重点实验室 |
| 通讯作者 | Zhai, Xiaofan; Duan, Jizhou |
| 作者单位 | 1.Chinese Acad Sci, Inst Oceanol, CAS Key Lab Marine Environm Corros & Biofouling, 7 Nanhai Rd, Qingdao 266071, Peoples R China 2.Pilot Natl Lab Marine Sci & Technol Qingdao, Open Studio Marine Corros & Protect, 1 Wenhai Rd, Qingdao 266235, Peoples R China 3.Univ Chinese Acad Sci, 19 Jia Yuquan Rd, Beijing 100049, Peoples R China 4.Immanuil Kant Baltic Fed Univ, Inst Living Syst, A Nevskogo 14, Kaliningrad 236041, Russia 5.Chinese Acad Sci, Ctr Ocean Mega Sci, 7 Nanhai Rd, Qingdao 266071, Peoples R China |
| 第一作者单位 | 中国科学院海洋研究所 |
| 通讯作者单位 | 中国科学院海洋研究所 |
| 推荐引用方式 GB/T 7714 | Zhai, Xiaofan,Li, Ke,Guan, Fang,et al. Ultrasound-assisted synthesis of wear-resistant Zn-Ferrocene composite coatings with high anticorrosive properties in alkaline environments[J]. SURFACE & COATINGS TECHNOLOGY,2018,356:19-28. |
| APA | Zhai, Xiaofan.,Li, Ke.,Guan, Fang.,Wang, Nan.,Agievich, Maria.,...&Hou, Baorong.(2018).Ultrasound-assisted synthesis of wear-resistant Zn-Ferrocene composite coatings with high anticorrosive properties in alkaline environments.SURFACE & COATINGS TECHNOLOGY,356,19-28. |
| MLA | Zhai, Xiaofan,et al."Ultrasound-assisted synthesis of wear-resistant Zn-Ferrocene composite coatings with high anticorrosive properties in alkaline environments".SURFACE & COATINGS TECHNOLOGY 356(2018):19-28. |
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