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Stable LATP/LAGP double-layer solid electrolyte prepared via a simple dry-pressing method for solid state lithium ion batteries | |
Zhao, Erqing1; Ma, Furui1,2; Guo, Yudi3; Jin, Yongcheng1 | |
2016 | |
发表期刊 | RSC ADVANCES |
卷号 | 6期号:95页码:92579-92585 |
文章类型 | Article |
摘要 | In this paper, a NASICON-type Li1.3Al0.3Ti1.7(PO4)(3) (LATP)/Li1.3Al0.3Ge1.7(PO4)(3) (LAGP) bi-layer structured solid state electrolyte was successfully prepared via a simple dry pressing and post-calcination method. By adjusting the sintering temperature for LAGP starting materials, a dense and smooth LATP/LAGP double-layer solid state electrolyte with no defects was obtained. This electrolyte sample exhibits a high electrical conductivity of 3.4 x 10(-4) S cm(-1) and a negligible electronic conductivity of 9.6 x 10(-9) S cm(-1) at room temperature. In addition, the LATP/LAGP electrolyte also shows an excellent stability in air as well as chemical stability against Li. Moreover, an assembled LiFePO4/LATP-LAGP/Li coin-type battery employing LATP/LAGP as the solid state electrolyte can be suitably charged and discharged at a current rate of 0.1C at room temperature, and its low charge-discharge capacities are mainly attributed to the high electrolyte/electrode interfacial resistance of the cell. These results suggest that the LATP/LAGP bilayer electrolyte can be an alternative electrolyte for all-solid-state lithium-ion batteries. |
DOI | 10.1039/c6ra19415j |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000385389800052 |
引用统计 | |
文献类型 | 期刊论文 |
版本 | 出版稿 |
条目标识符 | http://ir.qdio.ac.cn/handle/337002/136161 |
专题 | 海洋环境腐蚀与生物污损重点实验室 |
作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao Key Lab Solar Energy Utilizat & Energy St, Qingdao 266101, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China |
推荐引用方式 GB/T 7714 | Zhao, Erqing,Ma, Furui,Guo, Yudi,et al. Stable LATP/LAGP double-layer solid electrolyte prepared via a simple dry-pressing method for solid state lithium ion batteries[J]. RSC ADVANCES,2016,6(95):92579-92585. |
APA | Zhao, Erqing,Ma, Furui,Guo, Yudi,&Jin, Yongcheng.(2016).Stable LATP/LAGP double-layer solid electrolyte prepared via a simple dry-pressing method for solid state lithium ion batteries.RSC ADVANCES,6(95),92579-92585. |
MLA | Zhao, Erqing,et al."Stable LATP/LAGP double-layer solid electrolyte prepared via a simple dry-pressing method for solid state lithium ion batteries".RSC ADVANCES 6.95(2016):92579-92585. |
条目包含的文件 | ||||||
文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | ||
Stable LATP_LAGP dou(2506KB) | 期刊论文 | 出版稿 | 限制开放 | CC BY-NC-SA | 浏览 |
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