Institutional Repository of Key Laboratory of Marine Environmental Corrosion and Bio-fouling, IOCAS
| Peroxidase-like activity of FeVO4 nanobelts and its analytical application for optical detection of hydrogen peroxide | |
Yu, Yanzhen1; Ju, Peng2,3 ; Zhang, Dun4; Han, Xiuxun2,3; Yin, Xiaofei1; Zheng, Li5; Sun, Chengjun1,6
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| 2016-10-05 | |
| 发表期刊 | SENSORS AND ACTUATORS B-CHEMICAL
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| 卷号 | 233页码:162-172 |
| 文章类型 | Article |
| 摘要 | In this paper, FeVO4 materials were prepared via a facile hydrothermal method under different pHs and developed as highly efficient biomimetic catalysts for the first time. Different FeVO4 materials with different crystal structures, morphologies and surface properties showed distinct peroxidase-like activities. Experimental results showed that the products obtained at pH = 4 (FeVO4-4) possessed a belt-like nano structure with a large BET specific surface area and exhibited the best intrinsic peroxidase-like activity compared to other FeVO4 materials. FeVO4-4 nanobelts (NBs) could efficiently catalyze the oxidation of 3,3',5,5'-tetramethylbenzidine (TMB) in the presence of H2O2 to generate a blue oxide. Based on the highly efficient catalytic activity of FeVO4-4 NBs, a novel system for optical determination of H2O2 was successfully established, and the detection limit of H2O2 could reach 0.2 M. FeVO4-4 NBs also exhibited excellent selectivity, reproducibility, long-term stability, and easy recovery property. Furthermore, a peroxidase mimetic mechanism of FeVO4-4 NBs was proposed based on the active species trapping experiments. This work developed a novel, accessible and highly sensitive system for visual detection of H2O2, making FeVO4-4 NBs a potential biomimetic catalysts in H2O2 detection and biomedical analysis. (C) 2016 Elsevier B.V. All rights reserved. |
| 关键词 | Fevo4 Nanobelts Peroxidase-like Activity Optical Determination Hydrogen Peroxide |
| DOI | 10.1016/j.snb.2016.04.041 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000396136800005 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 版本 | 出版稿 |
| 条目标识符 | http://ir.qdio.ac.cn/handle/337002/135948 |
| 专题 | 海洋环境腐蚀与生物污损重点实验室 |
| 作者单位 | 1.State Ocean Adm, Inst Oceanog 1, Marine Ecol Ctr, 6 Xianxialing Rd, Qingdao 266061, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, Lab Clean Energy Chem & Mat, 18 Tianshui Middle Rd, Lanzhou 730000, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, Qingdao Ctr Resource Chem & New Mat, 36 Jinshui Rd, Qingdao 266100, Peoples R China 4.Chinese Acad Sci, Inst Oceanol, Lab Marine Environm Corros & Biofouling, 7 Nanhai Rd, Qingdao 266071, Peoples R China 5.Qingdao Natl Lab Marine Sci & Technol, Lab Marine Ecol & Environm Sci, Qingdao 266071, Peoples R China 6.Qingdao Natl Lab Marine Sci & Technol, Lab Marine Drugs & Bioprod, Qingdao 266071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu, Yanzhen,Ju, Peng,Zhang, Dun,et al. Peroxidase-like activity of FeVO4 nanobelts and its analytical application for optical detection of hydrogen peroxide[J]. SENSORS AND ACTUATORS B-CHEMICAL,2016,233:162-172. |
| APA | Yu, Yanzhen.,Ju, Peng.,Zhang, Dun.,Han, Xiuxun.,Yin, Xiaofei.,...&Sun, Chengjun.(2016).Peroxidase-like activity of FeVO4 nanobelts and its analytical application for optical detection of hydrogen peroxide.SENSORS AND ACTUATORS B-CHEMICAL,233,162-172. |
| MLA | Yu, Yanzhen,et al."Peroxidase-like activity of FeVO4 nanobelts and its analytical application for optical detection of hydrogen peroxide".SENSORS AND ACTUATORS B-CHEMICAL 233(2016):162-172. |
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| 文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | ||
| Peroxidase-like acti（3499KB） | 期刊论文 | 出版稿 | 限制开放 | CC BY-NC-SA | 浏览 | |
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