Institutional Repository of Key Laboratory of Experimental Marine Biology, Institute of Oceanology, Chinese Academy of Sciences
| Speciation Analysis of Organotin Compounds in Sediment by Hyphenated Technique of High Performance Liquid Chromatography-Inductively Coupled Plasma Mass Spectrometry | |
Yu Zhen-Hua1,2; Zhang Jie1 ; Wang Xiao-Ru3
| |
| 2011-04-01 | |
| 发表期刊 | CHINESE JOURNAL OF ANALYTICAL CHEMISTRY
 |
| ISSN | 0253-3820 |
| 卷号 | 39期号:4页码:544-547 |
| 文章类型 | Article |
| 摘要 | The hyphenated technique of high performance liquid chromatography coupled with inductively coupled plasma mass spectrometry (HPLC-ICP-MS) was applied to the simultaneous determination of five organotin compounds in the sediment samples. Agilent TC-C18 column was selected, mobile phase of the HPLC was CH(3)CN : H(2)O : CH(3)COOH = 65 : 23 : 12 (V/V), 0. 05% triethylamine (TEA), pH=3. 0 at flow rate Of 0. 6 mL/min. 30% O(2)/Ar mixed gas was added to the make-up gas, which not only reduced the carbon build-up on the cones, but also protected the cones. To reduce solvent loading on the plasma, the double-pass spray-chamber was peltier cooled to-5 degrees C. The high RF power (1500 W) helped the samples to decompose completely. A mix standard solution of five mixed organotin compounds from 100 mu g/L to 1 mu g/L was used for the method assessment. The experimental results indicate that the correlaticin coefficient of calibration curves (R(2)) for each organotin compound was over 0. 998. The international standard reference PACS-2 samples were treated by supersonic extraction with mobile phase added 0. 2% tropolone. Two organotin compounds including dibutyltin chloride (DBT) and tributyltin chloride (TBT) were detected with method mentioned above. The values of dibutyltin chloride (DBT) and tributyltin chloride (TBT) were 0. 99 and 0. 83 mg/kg, respectively. The results showed good accordance with the certified values. The recoveries from the standard addition for five organtins were over 80%.; The hyphenated technique of high performance liquid chromatography coupled with inductively coupled plasma mass spectrometry (HPLC-ICP-MS) was applied to the simultaneous determination of five organotin compounds in the sediment samples. Agilent TC-C18 column was selected, mobile phase of the HPLC was CH(3)CN : H(2)O : CH(3)COOH = 65 : 23 : 12 (V/V), 0. 05% triethylamine (TEA), pH=3. 0 at flow rate Of 0. 6 mL/min. 30% O(2)/Ar mixed gas was added to the make-up gas, which not only reduced the carbon build-up on the cones, but also protected the cones. To reduce solvent loading on the plasma, the double-pass spray-chamber was peltier cooled to-5 degrees C. The high RF power (1500 W) helped the samples to decompose completely. A mix standard solution of five mixed organotin compounds from 100 mu g/L to 1 mu g/L was used for the method assessment. The experimental results indicate that the correlaticin coefficient of calibration curves (R(2)) for each organotin compound was over 0. 998. The international standard reference PACS-2 samples were treated by supersonic extraction with mobile phase added 0. 2% tropolone. Two organotin compounds including dibutyltin chloride (DBT) and tributyltin chloride (TBT) were detected with method mentioned above. The values of dibutyltin chloride (DBT) and tributyltin chloride (TBT) were 0. 99 and 0. 83 mg/kg, respectively. The results showed good accordance with the certified values. The recoveries from the standard addition for five organtins were over 80%. |
| 关键词 | High Performance Liquid Chromatography-inductively Coupled Plasma Mass Spectrometry Organotin Compounds Speciation Sediment |
| 学科领域 | Chemistry |
| DOI | 10.3724/SP.J.1096.2011.00544 |
| URL | 查看原文 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000292345600020 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.qdio.ac.cn/handle/337002/11945 |
| 专题 | 实验海洋生物学重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Oceanol, Qingdao 266071, Peoples R China 2.Qingdao Ctr Dis Control & Prevent, Qingdao 266033, Peoples R China 3.State Ocean Adm, Inst Oceanog 1, Qingdao 266061, Peoples R China |
| 第一作者单位 | 中国科学院海洋研究所 |
| 推荐引用方式 GB/T 7714 | Yu Zhen-Hua,Zhang Jie,Wang Xiao-Ru. Speciation Analysis of Organotin Compounds in Sediment by Hyphenated Technique of High Performance Liquid Chromatography-Inductively Coupled Plasma Mass Spectrometry[J]. CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,2011,39(4):544-547. |
| APA | Yu Zhen-Hua,Zhang Jie,&Wang Xiao-Ru.(2011).Speciation Analysis of Organotin Compounds in Sediment by Hyphenated Technique of High Performance Liquid Chromatography-Inductively Coupled Plasma Mass Spectrometry.CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,39(4),544-547. |
| MLA | Yu Zhen-Hua,et al."Speciation Analysis of Organotin Compounds in Sediment by Hyphenated Technique of High Performance Liquid Chromatography-Inductively Coupled Plasma Mass Spectrometry".CHINESE JOURNAL OF ANALYTICAL CHEMISTRY 39.4(2011):544-547. |
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